DRIFTS Study of Kinetics of Diffusion-Limited Adsorption of Ethane from Mixtures with Hydrogen by Cationic Forms of Zeolites |
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Authors: | V B Kazansky N A Sokolova |
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Institution: | (1) Zelinsky Institute of Organic Chemistry, Leninsky Prospect 47, Moscow, Russia |
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Abstract: | The diffusion-limited adsorption of individual ethane or of ethane from mixtures with hydrogen by thin pellets of NaA, CaA
and LiLSX zeolites or by thick layers of granulated zeolites was studied at room temperature. The rates of adsorption were
monitored by development of the bands from the symmetry forbidden C–H stretching vibrations that were not observed for gaseous
molecules. Diffusivity of individual ethane in the micropores of the thin NaA pellet obtained by this method is equal to 6
⋅ 10−16 m2/s. This value agrees well with that one previously reported in literature. For adsorption of pure ethane in the larger primary
micro pores of CaA or LiLSX only the lower limits of diffusivities were estimated. Diffusion-limited adsorption of ethane
from mixtures with hydrogen by the thicker layers of granulated zeolites is much slower and is limited by counterdiffusion
inside much larger channels between the zeolite granules. Estimation of diffusion coefficients of such counterdiffusion indicated
that they are by two orders of magnitude lower than those for diffusion in gaseous mixtures of similar composition.
This paper is dedicated to the memory of Professor Wolfgang Schirmer. |
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Keywords: | DRIFTS diffusion ethane-hydrogen mixtures zeolites |
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