| Synthesis and Crystal Structure of a Decanuclear Silver(Ⅰ)-thiolate Compound Ag_(10)S[S_2P(OEt)_2]_8 |
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| 引用本文： | 朱永宝,卢绍芳,黄小荥,黄子祥,吴锵金.Synthesis and Crystal Structure of a Decanuclear Silver(Ⅰ)-thiolate Compound Ag_(10)S[S_2P(OEt)_2]_8[J].中国化学,2004(7). |
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| 作者姓名： | 朱永宝 卢绍芳 黄小荥 黄子祥 吴锵金 |
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| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China (Nos. 29673046 and 29733090)，the Natural Science Foundation of Fujian Province (No. B96018) and the State Key Laboratory of Structural Chemistry. |
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| 摘 要： | Introduction Polynuclear Ag(I)-thiolate compounds are of interests due to their unique molecular structures and metal-metal interactions. There were some such compounds reported in literatures, including Ag8(6-S)(dtp)6 dtp=S2P(OEt)2] with Ag8] cube,1 {AgS2P(OC3H7)2]}6 with a Ag6] distorted octahedron,2 Ag11S(Et2dtc)9 Et2dtc=S2CN(C2H5)2] with a Ag11] cage of a 3-fold axis,3 and Ag14(6-S)(SPh)12(PPh3)8 4CH3OH13H2O with a Ag14S12] cage composed of a staggered Ag6] octahedr…
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