Advances in the gas-phase synthesis of organochloro derivatives of silicon, germanium, and tinvia dichlorosilylene |
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| Authors: | E A Chernyshev N G Komalenkova V G Bykovchenko |
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| Institution: | (1) State Research Center of the Russian Federation, State Scientific-Research Institute of Chemistry and Technology of Organoelement Compounds, 38 sh. Entuziastov, 111123 Moscow, Russian Federation |
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| Abstract: | The results of studies carried out in the past five years on the gas-phase synthesis of organochlorosilanes, pentachlorodisiloxanes,
organochlorogermanes, and organochlorostannanes at 400–550 °C in the presence of hexachlorodisilane or 1,1-dichloro-1-silacyclopent-3-ene
as sources of dichlorosilylene are summarized.
Dedicated to the memory of Academician M. E. Vol'pin timed to his 75th birthday.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1063–1070, June, 1998. |
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| Keywords: | alkylchlorosilanes alkenylchlorosilanes pentachlorodisiloxanes alkenylchlorogermanes arylchlorogermanes organylchlorostannanes gas-phase synthesis hexachlorodisilane dichlorosilylene dichlorogermylene dichlorostannylene |
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