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STRUCTURAL FEATURE AND EXCHANGE KINETICS OF CARBOXYLATED POLYPROPYLENE ION EXCHANGE RESIN
引用本文:吴锦远,杨超雄,杨冲. STRUCTURAL FEATURE AND EXCHANGE KINETICS OF CARBOXYLATED POLYPROPYLENE ION EXCHANGE RESIN[J]. 高分子科学, 1987, 0(1): 12-19
作者姓名:吴锦远  杨超雄  杨冲
作者单位:Guangzhou Institute of Chemistry,Academia Sinica,Guangzhou,Guangzhou Institute of Chemistry,Academia Sinica,Guangzhou,Guangzhou Institute of Chemistry,Academia Sinica,Guangzhou
摘    要:The present article deals with the exchange process of bivalent metal ions, such as Zn~(2+), Cd~(2+) and Hg~(2+), etc., taken up by non-crosslinked earboxylated polypropylene (CPP) resin. The control factor of the exchange rate deduced from the kinetic data is governed basically by the chemical reaction rather than the mass transfer effect particle diffusion and/or liquid film diffusion. In solution, all the graft chains in the outer shell of a CPP resin could form a "quasi-macromolecular solution" domain. This opinion further demonstrates the structural pattern of CPP resin proposed in earlier paper.

收稿时间:1985-04-04

STRUCTURAL FEATURE AND EXCHANGE KINETICS OF CARBOXYLATED POLYPROPYLENE ION EXCHANGE RESIN
WU Chinyung,YANG Chaoshiung,YANG Chong. STRUCTURAL FEATURE AND EXCHANGE KINETICS OF CARBOXYLATED POLYPROPYLENE ION EXCHANGE RESIN[J]. Chinese Journal of Polymer Science, 1987, 0(1): 12-19
Authors:WU Chinyung  YANG Chaoshiung  YANG Chong
Affiliation:Guangzhou Institute of Chemistry; Academia Sinica; Guangzhou
Abstract: The present article deals with the exchange process of bivalent metal ions, such as Zn2+, Cd2+ and Hg2+, etc., taken up by non-crosslinked earboxylated polypropylene (CPP) resin. The control factor of the exchange rate deduced from the kinetic data is governed basically by the chemical reaction rather than the mass transfer effect particle diffusion and/or liquid film diffusion. In solution, all the graft chains in the outer shell of a CPP resin could form a "quasi-macromolecular solution" domain. This opinion further demonstrates the structural pattern of CPP resin proposed in earlier paper[1].
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