Beiträge zur Chemie der Pyrrolpigmente, 13. Mitt. Die thermische Stabilität der geometrischen Isomeren von Arylmethylidenpyrrolinonen |
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Authors: | Doz Dr Heinz Falk Karl Grubmayr Otmar Hofer Franz Neufingerl José M Ribó |
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Institution: | (1) Lehrkanzel für Organische Chemie, Universität Wien, Währinger Straße 38, A-1090 Wien, Österreich |
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Abstract: | From kinetic studies and the investigation of several model compounds it has been deduced that the interconversion of (E)- and (Z)-arylmethylidenepyrrolinones proceeds via a thermal accessible dipolar (singlet) state thus being analogous to the many known thermal (Z)—(E)-isomerizations. There is a pronounced dependence of this reaction on the solvent and the substitution of the aryl part of the molecule; the equilibrium position between (Z)- and (E)-isomers is determined by the substituent in position 4 of the pyrrolinone ring.
Mit 3 Abbildungen 12. Mitt.:H. Falk undJ. M. Ribó, Mh. Chem.107, 307 (1976). |
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