| D-葡萄糖衍生的新型多官能团取代手性丁醛的合成 |
| |
| 引用本文： | 邓林凤,周骁汉,秦勇,张丹.D-葡萄糖衍生的新型多官能团取代手性丁醛的合成[J].合成化学,2017,25(5):403-407. |
| |
| 作者姓名： | 邓林凤 周骁汉 秦勇 张丹 |
| |
| 作者单位： | 四川大学 华西药学院，四川 成都 610041 |
| |
| 基金项目： | 四川大学优秀青年基金资助项目 |
| |
| 摘 要： | 报道了一种基于D-葡萄糖的多官能团取代手性丁醛的合成方法。以D-葡萄糖为原料，经官能团化和两次高碘酸钠氧化切断策略，合成了一种D-葡萄糖衍生的新型多官能团取代手性丁醛合成子，其结构经1H NMR, 13C NMR和LC-MS(ESI)表征。
|
| 关 键 词： | D-葡萄糖 多官能团 手性丁醛 手性合成子 合成 |
| 收稿时间： | 2016-10-26 |
Synthesis of A Novel D-glucose Derived Poly-functionalized Chiral Butyroaldehyde |
| |
| DENG Lin-feng,ZHOU Xiao-han,QIN Yong,ZHANG Dan.Synthesis of A Novel D-glucose Derived Poly-functionalized Chiral Butyroaldehyde[J].Chinese Journal of Synthetic Chemistry,2017,25(5):403-407. |
| |
| Authors: | DENG Lin-feng ZHOU Xiao-han QIN Yong ZHANG Dan |
| |
| Institution: | West China School of Pharmacy, Sichuan University, Chengdu 610041, China |
| |
| Abstract: | A method for the synthesis of poly-functionalized chiral butyroaldehyde building block derived from D-glucose was reported.Starting from D-glucose, by functional group manipulation and double NaIO4 oxidative cleavage strategies, the poly-functionalized chiral butyroaldehyde building block was synthesized.The structure was characterized by 1H NMR, 13C NMR and LC-MS(ESI). |
| |
| Keywords: | D-glucose poly-function chiral butyroaldehyde chiral building block synthesis |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《合成化学》浏览原始摘要信息 |
| 点击此处可从《合成化学》下载免费的PDF全文 |
|
