Catalytic Effect of Reverse Micelles of a Cationic Surfactant on the Reaction of Calix[4]resorcinolarenes with 4-Nitrophenyl Bis(chloromethyl)phosphinate |
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| Authors: | Zhil'tsova E. P. Kudryavtseva L. A. Timosheva A. P. Kharitonov N. I. Konovalov A. I. |
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| Affiliation: | (1) Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia |
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| Abstract: | The presence of the aminomethyl fragment in the calix[4]resorcinolarene molecule favors its phosphorylation in chloroform. Reverse micelles of (2-hydroxyethyl)dimethylpentadecylammonium bromide catalyze this reaction, the catalytic effect being dependent on the length of the hydrocarbon chain of a calixarene and detergent concentration. |
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