Cyclopentane-1,3-dione bis(4-methylthiosemicarbazone) monohydrochloride as a spectrophotometric reagent for the determination of chlorate in perchloric acid medium |
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Authors: | M.Roman Ceba J.C.Jiménez Sánchez T.Galeano Díaz |
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Affiliation: | Department of Analytical Chemistry, Faculty of Science, University of Extremadura, Badajoz, Spain |
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Abstract: | 1,3-Cyclopentanedione bis(4-methylthiosemicarbazone) monohydrochloride produces colored solutions with chlorate ions in strongly acid medium. The yellow color obtained has been used to propose a spectrophotometric method of C103? determination in the concentration range 0.5–6.0 ppm (molar absorptivity 1.26 × 104 liters mol?1 cm?1 at a wavelength of 397 nm). |
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