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AROMATIZATION OF PROPYLENE OVER Ga_2O_3/HZSM-5 CATALYSTS
摘    要:A series of Ga_2O_3/HZSM-5 catalysts of different Ga content havebeen prepared by physical mixing method.Propylene aromatization over thesecatalysts carried out in the pulse-microreaetor and flow-microreactor shows thatthe reaction depends strongly on the acidity of the zeolite.Ga_2O_3 supported onHZSM-5 points to a considerable effect on its activity and selectivity only whenreaction temperature is higher than 773K.Over Ga_2O_3/HZSM-5 pretreated inhydrogen at relatively high temperature,the activity and selectivity for propy-iene aromatization increase remarkably.The optimum pretreatment conditionfor catalyst is in hydrogen at 773K for 2h.And the suitable Ga content andspace velocity are about 1wt% and 8-12g.mol~(-1).h respectively.Also,an ap-proach is made to the mechanism of propylene aromatization.

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