Reductive carbonylation of nitrobenzene over Pd/Fe/I2/Py and Pd/C/Fe/I2/Py catalytic systems |
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Authors: | Jadwiga Skupi ska, Monika Karpi ska, Leszek Wachowski Magdalena Hofman |
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Affiliation: | (1) Faculty of Chemistry, The University of Warsaw, 2-093 Warsaw, Pasteura 1, Poland |
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Abstract: | A simple catalytic system containing metallic palladium, iron and iodine has been shown to be very active in the carbonylation of nitrobenzene to carbamate. The influence of the components of the catalytic system studied on its selectivity and activity has been established. It has been found that the catalytic activity of palladium supported on carbon (using both lignite coal and bituminous coal) was not lower than the activity of metallic palladium. This revised version was published online in August 2006 with corrections to the Cover Date. |
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Keywords: | palladium Carbonylation nitrobenzene Pd/C |
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