Carbon-dot confined in graphene-analogous boron nitride for enhanced oxidative desulfurization |
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Affiliation: | 1. Department of Chemistry, Payame Noor University (PNU), 19395-4697, Iran;2. Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad, Iran;3. Department of Environmental Health Engineering, Neyshabur University of Medical Sciences, Neyshabur, Iran;4. Department of Chemistry, Faculty of Sciences, Bojnourd Branch, Islamic Azad University, Bojnourd, Iran |
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Abstract: | As of late, graphene-like boron nitride (g-BN), has been created another schedule as aerobic catalysis, and have a profound effect on the key performance of the catalyst. In this paper, C-nanodots with low resistivity, were bounded through g-BN (C-dots/g-BN) to help electron versatility by a straight forward one-pot pathway. C-dots were bounded in graphene-analogous boron nitride (g-BN) via a one-step, in situ process at increased temperature, which could upgrade the interactions of C-dots and control the dimensions of C-dots in the scope of nearly 4–5 nm. The results demonstrated that C-dots/g-BN has a superior execution in high-impact oxidation of dibenzothiophene (DBT) in fuel oil with a reactant movement of 93.5%. Estimation showed that hydroxyl radicals produced from H2O2 as a result of the interaction with C-dots ended up a proficient catalyst in the framework. The C-dots had a synergetic impact to enhance the proficiency of H2O2 in the catalyst. The portrayal results showed that piece of the DBT was oxidized to its comparing sulfoxide which requires less oxidant than sulfone. Both of the oxidation items could be extracted in the oil phase on the catalyst. |
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Keywords: | Graphene-like boron nitride C-nanodot Dibenzothiophene Fuel oil |
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