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Removal of Eosin dye from simulated media onto lemon peel-based low cost biosorbent
Institution:1. School of Chemistry, Faculty of Basic Sciences and Mathematics, Minhaj University Lahore, Lahore 54700, Pakistan;2. Department of Allied Health Sciences, Superior University Lahore, Lahore 54700, Pakistan;3. Department of Chemistry, Forman Christian College Lahore, Lahore 54700, Pakistan;4. Department of Chemistry, University of Punjab, Lahore 54700, Pakistan;5. Department of Physics, University of Punjab, Lahore 54700, Pakistan;6. Department of Chemistry, Faculty of Science, King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia
Abstract:Synthetic dyes from different sources (wastewater and effluents) can be harmful to the environment even at minor quantity. Low cost natural biosorbent have been proved beneficial for water treatment and have excellent capability for the elimination of certain dyes from aqueous media. The present study purposed to utilize lemon peel as a natural sorbent for eosin dye in an aqueous media. The biosorbent were analyzed utilizing fourier transform infrared spectroscopy, scanning electron microscope (SEM), energy-dispersive X-ray analysis (EDX) and surface area analyzer (BET). The batch adsorption approach was carried out to optimize the basic parameters affecting the sorption phenomena. Anionic dye, eosin, was removed by adsorption utilizing lemon peel, as an biosorbent and such adsorption are affected by different physical factors i.e adsorbent dose, contact time, temperature etc. Freundlich and Langmuir's adsorption isotherm models are used to verify the results. The monolayer adsorption capacity was 8.240 mg/g at 30 °C that is calculated from Langmuir isotherm. The adsorption process is exothermic, shown by calculations thermodynamic parameters. Kinetics studies have represented that the adsorption process could be better explained by pseudo-second-order kinetics. All the parameters of biosorbent were compared with each other and proved that lemon peel, which is readily available, economic biosorbent, for the removal of eosin dye from the aqueous media.
Keywords:Lemon peel  Dye  Langmuir and Freundlich constants  SEM  FTIR  EDX
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