Polyfuryl(aryl)alkanes and their derivatives. 7. New recyclization and cyclization reactions in the 2-hydroxyaryldifurylmethane series |
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Authors: | A V Butin G D Krapivin V E Zavodnik V G Kul'nevich |
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Institution: | (1) Krasnodar Polytechnical Institute, 350072 Krasnodar |
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Abstract: | Reaction of 2-hydroxybenzaldehydes with -methylfuran (sylvan) under acid-catalysis conditions was investigated. It is shown that the reaction does not stop at the step involving formation of 2-hydroxyarylfuryl-methanes but proceeds further with opening of one of furan rings and recyclization to 3-furylbenzo-furan derivatives. The latter in turn undergo transformations that lead to new heterocyclic systems — 5,6-dihydro-2,4-dimethyl-4-(5-methyl-2-furyl)-4H-benzob]furo2,3-h]cyclopentab]furans. Data from the IR, PMR, and mass spectra, alternative synthesis, and x-ray diffraction analysis were used to confirm structures of the synthesized compounds.For Communication 6 see 1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 616–626, May, 1993. |
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