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New chiral cyclopalladated complexes based on the pinane and bornane imines |
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| Authors: | A. V. Kuchin Ya. A. Gur’eva L. L. Frolova I. N. Alekseev O. A. Zalevskaya |
| Affiliation: | 1. Institute of Chemistry, Komi Scientific Center of the Ural Branch of the Russian Academy of Sciences, 48 ul. Pervomaiskaya, 167982, Syktyvkar, Russian Federation 2. Syktyvkar State University, 55 Octyabr’skii prosp., 167001, Syktyvkar, Russian Federation |
| Abstract: | 2α-Hydroxypinan-3-one imino derivatives react with lithium tetrachloropalladate to form palladacycles, while similar bornane derivative undergo cyclopalladation only when treated with palladium acetate. |
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