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Molybdenum hexacarbonyl-catalyzed condensation of malononitrile with ketones and aldehydes
Authors:R. I. Khusnutdinov  N. A. Shchadneva  Yu. Yu. Mayakova  T. M. Oshnyakova  U. M. Dzhemilev
Affiliation:1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation
Abstract:Molybdenum hexacarbonyl activated with pyridine or morpholine catalyzes the condensation of malononitrile with ketones and aldehydes at 140 °C, which leads to alkylidenemalononitriles in 75–100% yield.
Keywords:
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