Molybdenum hexacarbonyl-catalyzed condensation of malononitrile with ketones and aldehydes |
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Authors: | R. I. Khusnutdinov N. A. Shchadneva Yu. Yu. Mayakova T. M. Oshnyakova U. M. Dzhemilev |
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Affiliation: | 1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation
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Abstract: | Molybdenum hexacarbonyl activated with pyridine or morpholine catalyzes the condensation of malononitrile with ketones and aldehydes at 140 °C, which leads to alkylidenemalononitriles in 75–100% yield. |
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