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Cu2O-coated polystyrene microsphere materials with enhanced photo- and photoelectro-catalytic activity
Authors:Xin Zhang  Sha Yu  Yang Cao  Lin Chen  Tai Zhao  Fengchun Yang
Institution:1. Institute of Analytical Science/Shaanxi Provincial Key Laboratory of Electroanalytical Chemistry, Northwest University, Xi’an, Shaanxi, 710069, People’s Republic of China
2. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an, Shaanxi, 710069, China
Abstract:Cuprous oxide microsphere material was fabricated by electrochemical deposition using polystyrene particles as template. The samples are characterized by scanning electron microscope (SEM), X-ray diffraction, and UV–vis spectrophotometer. The SEM image shows the morphology and size of the microspheres, and the thickness of covered Cu2O layer is about 100 nm. Due to the unique microspherical structure, the surface area is larger, and the optical absorption is better in Cu2O microsphere material than in bulk Cu2O film, which makes the degradation of methylene blue faster and photoelectrocatalytic oxidation of glucose stronger on Cu2O microsphere material than on bulk Cu2O film under visible light illumination. The enhanced photo- and photoelectro-catalytic activity makes the Cu2O microsphere material more suitable for solar applications.
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