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Raising the spin of Fe(III)7 disklike clusters: the power of molecular spin frustration
Authors:Mukherjee Shreya  Bagai Rashmi  Abboud Khalil A  Christou George
Institution:Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA.
Abstract:Two clusters with a new type of Fe(III)(7) disklike structure have been prepared; in contrast to other Fe(III)(7) disks, they possess high ground-state spins (S = (15)/(2) and (21)/(2)), which have been rationalized by analysis of the spin-frustration patterns.
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