Raising the spin of Fe(III)7 disklike clusters: the power of molecular spin frustration |
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Authors: | Mukherjee Shreya Bagai Rashmi Abboud Khalil A Christou George |
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Institution: | Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA. |
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Abstract: | Two clusters with a new type of Fe(III)(7) disklike structure have been prepared; in contrast to other Fe(III)(7) disks, they possess high ground-state spins (S = (15)/(2) and (21)/(2)), which have been rationalized by analysis of the spin-frustration patterns. |
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