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Synthesis of ThCr2Si2-type arsenides from Bi flux
Authors:Thompson Corey M  Kovnir Kirill  Eveland Stephanie  Herring Mitchell J  Shatruk Michael
Institution:Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, FL 32306, USA.
Abstract:LaCo(2)As(2) can be synthesized as pure crystalline material by annealing a mixture of elements in Bi flux. The reaction, however, is accompanied by the incorporation of a small quantity of Bi into the structure and the formation of vacancies in the Co sublattice, which lead to substantial changes in structural and magnetic properties of the material.
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