Synthesis of ThCr2Si2-type arsenides from Bi flux |
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Authors: | Thompson Corey M Kovnir Kirill Eveland Stephanie Herring Mitchell J Shatruk Michael |
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Institution: | Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, FL 32306, USA. |
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Abstract: | LaCo(2)As(2) can be synthesized as pure crystalline material by annealing a mixture of elements in Bi flux. The reaction, however, is accompanied by the incorporation of a small quantity of Bi into the structure and the formation of vacancies in the Co sublattice, which lead to substantial changes in structural and magnetic properties of the material. |
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