Interaction of Methane and Oxygen with the Surface of Manganese Oxide-Containing Catalysts |
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Authors: | Bezrukov E. V. Kurina L. N. |
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Affiliation: | (1) Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, 3 Akademicheskii Prospekt, 634021 Tomsk, Russia;(2) Tomsk State University, 36 Lenina Prospekt, 634050 Tomsk, Russia |
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Abstract: | We used pulsed reduction and temperature programmed oxidation to study the interaction of methane and oxygen with the surface of manganese oxide-containing catalysts. We hypothesized that during oxidative dimerization of methane, the phase supplying strongly bound oxygen for selective methane coupling is an acceptor for weakly bound oxygen of the phase catalyzing exhaustive oxidation. |
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Keywords: | oxidative dimerization of methane manganese oxide sodium silicate oxygen methane |
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