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Synthesis of a pyrrolone-type polymer containing anthraquinone units in molten antimony trichloride
Authors:Maria Bruma  C S Marvel
Abstract:1,2,5,6-Tetraaminoanthraquinone and 1,4,5,8-naphthalenetetracarboxylic acid dianhydride react in molten antimony trichloride to give a soluble polypyrrolone structure with an inherent viscosity of 0.4–0.7. Polymers having the viscosity of 0.7 can be wetspun into fibers from molten antimony trichloride or from methanesulfonic acid; also the polymer can be reduced with sodium dithionite in alkaline aqueous dimethyl sulfoxide to give a viscous solution which can be spun into brittle fibers.
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