| 罗丹明-三嗪衍生物的合成及探针性质 |
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| 引用本文： | 陈义,张艳,曾晞,牟兰,李俊,孙强,张建新,卫钢.罗丹明-三嗪衍生物的合成及探针性质[J].高等学校化学学报,2013,34(7):1598-1605. |
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| 作者姓名： | 陈义 张艳 曾晞 牟兰 李俊 孙强 张建新 卫钢 |
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| 作者单位： | 1. 贵州大学化学与化工学院, 贵州省大环化学及超分子化学重点实验室, 贵阳 550025;
2. 中国科学院贵州省天然产物化学重点实验室, 贵阳 550002;
3. 澳大利亚联邦科学与工业研究组织, 材料科学与工程分部, 悉尼 2070 |
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| 基金项目： | 国家自然科学基金(批准号: 21165006);教育部"春晖计划"项目(批准号: Z2011033)和贵州省国际合作项目(批准号: 20107002)资助. |
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| 摘 要： | 在控制反应温度的条件下, 用罗丹明B酰肼(或罗丹明B乙二胺)选择性分步取代三聚氯氰环上的活性氯, 合成了系列罗丹明-三嗪衍生物. 考察了不同取代获得的衍生物的探针识别性能, 发现所制备的衍生物能高灵敏、高选择性地识别Al3+, Cr3+或Cu2+离子, 是一类性能良好的金属离子荧光和比色增强型探针.
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| 关 键 词： | 罗丹明衍生物 三聚氯氰 荧光探针 |
| 收稿时间： | 2013-02-27 |
Synthesis and Probe Properties of Rhodamine-triazine Derivatives |
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| CHEN Yi,ZHANG Yan,ZENG Xi,MU Lan,LI Jun,SUN Qiang,ZHANG Jian-Xin,WEI Gang.Synthesis and Probe Properties of Rhodamine-triazine Derivatives[J].Chemical Research In Chinese Universities,2013,34(7):1598-1605. |
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| Authors: | CHEN Yi ZHANG Yan ZENG Xi MU Lan LI Jun SUN Qiang ZHANG Jian-Xin WEI Gang |
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| Institution: | 1. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China;
2. Key Laboratory of Chemistry for Natural Products of Guizhou Province and Chinese Academy of Sciences, Guiyang 550002, China;
3. CSIRO Materials Science and Engineering, Lindfield, NSW Sydney 2070, Australia |
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| Abstract: | A series of rhodamine-triazine derivatives was synthesized through the substitution of active chlorine of cyanuric chloride step by step with rhodamine hydrazide(or rhodamine ethylenediamine). The recognition performances of derivatives were studied. Different substituted derivatives can recognize Al3+, Cr3+ or Cu2+ with high sensitivity and selectivity. They were a kind of good performance of metal ion fluorescence and color enhanced probes. |
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| Keywords: | Rhodamine derivative Cyanuric chloride Fluorescence probe |
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