| 胺氧化羰基化合成脲的研究进展 |
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| 引用本文： | 曹彦伟,张雪华,何林. 胺氧化羰基化合成脲的研究进展[J]. 分子催化, 2020, 34(2): 182-192 |
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| 作者姓名： | 曹彦伟 张雪华 何林 |
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| 作者单位： | 中国科学院兰州化学物理研究所,盐城师范学院,中国科学院兰州化学物理研究所 |
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| 基金项目： | 国家自然科学基金项目（面上项目，重点项目，重大项目） |
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| 摘 要： | CO是一种廉价、丰富且有用的C1分子,将其作为羰基源参与胺氧化羰基化反应是有机化学中一类重要的反应.近年来,采用胺氧化羰基化合成脲类化合物的技术路线备受关注.我们综述了催化剂参与的胺氧化羰基化合成脲类化合物的研究现状,还对胺氧化羰基化反应的发展趋势进行了展望.
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| 关 键 词： | 一氧化碳，胺，氧化羰基化，脲 |
| 收稿时间： | 2020-04-20 |
| 修稿时间： | 2020-04-23 |
Recent Advance in Synthesis of Urea by Oxidative Carbonylation of Amine |
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| CAO Yan-wei,ZHANG Xue-hua and HE Lin. Recent Advance in Synthesis of Urea by Oxidative Carbonylation of Amine[J]. Journal of Molecular Catalysis (China), 2020, 34(2): 182-192 |
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| Authors: | CAO Yan-wei ZHANG Xue-hua HE Lin |
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| Affiliation: | Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences,Yancheng Teachers University,Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences |
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| Abstract: | CO is a an inexpensive, abundant and useful C1 building block. It is an important transformation in organic chemistry to use CO as a carbonyl source to participate in the oxidation carbonylation of amine. Synthesis of urea and its derivatives by the oxidation carbonylation of amine has attracted much attention in recent year. This review intends to offer a detailed introduction of recent progress on the synthesis of urea by catalytic oxidative carbonylation of amines. Moreover, the development tendency for oxidative carbonylation of amine are also discussed. |
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| Keywords: | CO amine oxidative carbonylation urea |
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