Structural Effects in the Mitsunobu Reaction of Calix[4]arene with Benzylic and Allylic Alcohols [1] |
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| Authors: | Wang Jianshe Gutsche C David |
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| Institution: | (1) Department of Chemistry, Texas Christian University, Fort Worth, Texas, 76129 |
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| Abstract: | A study of the Mitsunobu reaction involving calix4]arene and a series of benzylic and allylic alcohols reveals the structural effect of the alcohol component on the distribution between Oand C-alkylation of the phenol component in the formation of aryl alkyl ethers and p-alkylated phenols, respectively. |
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| Keywords: | Calix[4]arene Mitsunobu reaction O-alkylation C-alkylation ambident anion |
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