Interaction of push–pull tert-enamines with phenylglyoxal |
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| Authors: | Dmitry A. Sibgatulin Dmitry M. Volochnyuk Aleksander N. Kostyuk Sergey P. Ivonin Andriy V. Lapandin |
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| Affiliation: | (1) Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Murmanska 5, 02094 Kiev-94, Ukraine;(2) PBMR Inc., Murmanska 1, 02094 Kiev-94, Ukraine; |
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| Abstract: | Abstract The reaction of push–pull enamines with 1,2-biselectrophilic phenylglyoxal was investigated. Phenylglyoxal was found to react depending on the structure of the push–pull enamine, affording either a hydroxyalkylation product at the methyl group or the cyclic product via participation of the methyl group and the β-carbon of the enamine. |
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