| C_(60)高压相变的拉曼光谱研究 |
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| 引用本文： | 蓝国祥,林远坤,王华馥,徐知三,盛蓉生.C_(60)高压相变的拉曼光谱研究[J].光散射学报,1992,4(2):93-96. |
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| 作者姓名： | 蓝国祥 林远坤 王华馥 徐知三 盛蓉生 |
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| 作者单位： | [1]南开大学物理系，天津300071 [2]武汉大学分析测试中心，武汉430072 |
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| 摘 要： | 本文对非静水压淬火的 C_(60)样品进行了拉曼光谱研究。在14.8GPa 以上,C_(60)的1468cm~(-1)特征峰的频率和线宽保持不变,这是 fullerite 相己转变成“透明相”的拉曼光谱证据。在32GPa 以上,原 C_(60)的散射峰全部消失,只观察到两个新的弥散的弱散射峰。表明 C_(60)原子团簇已倒塌或严重畸变。
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| 关 键 词： | C_(60) 高压相变 拉曼散射 |
Raman Spectra Study of the Pressure—induced Phase Transition in C_(60) |
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| Lan Gaoxiang Lin Yuankun Wand Huafu.Raman Spectra Study of the Pressure—induced Phase Transition in C_(60)[J].Chinese Journal of Light Scattering,1992,4(2):93-96. |
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| Authors: | Lan Gaoxiang Lin Yuankun Wand Huafu |
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| Abstract: | The non—hydrostatic pressure—quenched C_(60) has been investigated by Ra- man scattering.Above 14.8 GPa,the frequency and widthof the characteristic peak (1468 cm~(-1)) of C_(60) remain constant,which is evident that C_(60) fullerite phase transforms into an“transparent phase”.Above 32 GPa,all Raman peaks of the starting C_(60) disap- peared and only two new diffuse and weak peaks were observed,which indicated that C_(60) molecules were collapsed or distorted. |
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| Keywords: | C_(60) pressure—induced phase transition Raman scattering |
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