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Hahn-echoes from N in solids by the stray-field method: prospects for imaging using Long Echo-Train Summation
Authors:Edward W. Randall   Andrei A. Samoilenko  Riqiang Fu
Affiliation:

a Department of Chemistry, Queen Mary and Westfield College, London E1 4NS, UK

b Institute of Chemical Physics, Russian Academy of Sciences, 117977 Moscow, Russian Federation

c The National High Magnetic Field Laboratory, Florida State University, 1899 East Paul Dirac Drive, Tallahassee, FL 32310, USA

Abstract:We have observed Hahn-echoes resulting from Powles–Mansfield pulse-sequences for a variety of nitrogen containing solids which exhibit a range of 14N electric quadrupole coupling constants (Cq) from 0 to 4.9 MHz. Long echo-decays were frequently obtained which allowed the collection of many echoes in one echo-train, so that the method of Long Echo-Train Summation (LETS), could be used to accumulate signal. A one-dimensional STRAFI-profile is shown for solid ammonium nitrate. The spatial resolution is discussed as a function of Cq.
Keywords:Hahn-echoes   14N   Solids   Stray-field   Imaging   LETS
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