The Reaction of Benzothiazolesulfenamide with Phospiiorus-Containing Reagents |
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| Authors: | Jing-Lin Zhang Xiao-Bo Ma |
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| Affiliation: | Institute of Organic Synthesis, Huazhong Normal University , wuhan , Hubei , P.R.C. |
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| Abstract: | Abstract T. Sigeru reported the reaction of 2-benzothiazolesulfen-amide with phosphites, but other P-reagents have not been used. we found that this compound can react with tris(dialkylamino)phosphines or bis(dialkylamino)phosphites to give products (I). No S-N bond cleavage was observed in the reaction performed as described by T. Sigeru. In the presence of subetituent in amino group, the reaction proceeds differently. |
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