Reaction of Trialkylphosphine Carbon Disulfide Adducts with Cyclopentadienones |
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| Authors: | Nickolay I Tyryshkin Viktor V Gavrilov Alexandra V Fuzhenkova |
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| Institution: | Butlerov Chemical Research Institute, Kazan State University , Lenin Str. 18, Kazan, 420008, Russia |
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| Abstract: | Abstract It has been known more than for 100 year that triethylphosphine forms the 1:1 adducts with carbon disulfide and isothiocyanates. However, little is know on the reaction of the adducts and the formation of reactive alkylidenephosphoranes was recently reported by the reaction of adducts with electron-poor double bonds. |
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