Homolytical Reaction Peculiarities of Phosphororganic Compounds |
| |
| Authors: | A. I. Rakhimov A. A. Ozerov A. O. Litinskij S. L. Rysin O. P. Buzinova |
| |
| Affiliation: | Volgograd Polytechnical Institute , Lenin pst 28, Volgograd , 400066 , USSR |
| |
| Abstract: | Abstract The influence of the transient cyclic radical structure on the reactivity of unsaturated compounds in the processes of homolytical phosphorylation, and allyl and vinyl-phosphonates in the processes of homolytical perfluoro-alkylation is shown by the MINDO/3 method of quantum chemistry computations. The addition of allylderivatives of amides and esters of carbonic, aminocarbonic and carbamino-acids to phosphocentric radicals yields five-membered cyclic radical structures with NH- and O-heteroatoms in the cycle: |
| |
| Keywords: | |
|
|
