Reactivity of Conjugate Bases of Hydridophosphoranes. Synthesis of New Phosphoranes Involving P-P Bonds |
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Authors: | L. Lamande A. Munoz |
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Affiliation: | UA au CNRS N° 454, Université Paul Sabatier , 118 route de Narbonne, 31062 , Toulouse , Cedex , France |
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Abstract: | Abstract Hydridophosphoranes 1, 2 react, in presence of triethylamine, with phenyldichlorophosphine, diphenylchlorophosphine and the chlorophosphorane 3 giving unusual phosphoranes bearing P-P bonds. These last have been isolated and their structure has been determined by NMR spectroscopy. |
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