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Reactions of Hydrazonoyl Halides 41: 1 Synthesis of 1,2,4-Triazoles, 2,3-Dihydro-1,3,4-thiadiazoles,and Triazolo[4, 3-a]pyrimidines
Authors:Abdou O. Abdelhamid  Ahmed H. Elghandour  Ahmed M. Hussein  Yasser H. Zaki
Affiliation:1. Department of Chemistry , Faculty of Science, Cairo University (Beni-Suef Branch) , Beni-Suef , Egypt;2. Department of Chemistry , Faculty of Science, Cairo University , Giza , Egypt
Abstract:

Triazoles, thiadiazoles, and triazolo[4, 3-a]pyrimidines were synthesized via reaction of hydrazonoyl halides with each of 3-methyl-4-(methylthiothioxomethyl)-2-pyrazolin-5-one, 3-methyl-4-[methylthio(phenylamino)methyl]-2-pyrazolin-5-one, and pyrimidine-2-thiones. Structures of the newly synthesized compounds were elucidated on the basis of elemental analysis, spectral data, and alternative-methods synthesis whenever possible.
Keywords:1,2,4-Triazoles   2,3-dihydro1,3,4-thiadiazolines  hydrazonoyl halides  triazolino[4, 3-a]pyrimidines
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