Phosphorus Version of the Fritsch-Buttenberg-Wiechell Reaction |
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| Authors: | Masaaki Yoshifuji Shigekazu Ito |
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| Institution: | 1. Department of Chemistry , Graduate School of Science, Tohoku University , Aoba , Sendai , Japan;2. Department of Applied Chemistry , Graduate School of Science and Engineering , Tokyo |
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| Abstract: | Abstract Utilizing phosphorus version of the Fritsch-Buttenberg-Wiechell (FBW) reaction, arylphosphaalkynes are prepared from 2,2-dihalo-1-aryl-1-phosphaalkenes, and theoretical calculations were carried out to obtain some basic insight into intramolecular rearrangement in the phosphorus system of interest. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental resource: Density functional theory (DFT) and ab initio MP2 calculations.] Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfer, and Silicon for the following free supplemental files: Additional tables, figures, and references.] |
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| Keywords: | Phosphaalkyne Fritsch-Buttenberg-Wiechell reaction intramolecular rearrangement DFT calculation 2 4 6-tri-t-butylphenyl vibration analysis |
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