1. Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences , 1, Favorsky Street, 664033, Irkutsk, Russia;2. Utrecht University , Padualaan 8, 3584 CH, Utrecht, The Netherlands
Abstract:
Abstract Nucleophilic addition of phosphide anions generated from phosphorus red or phosphine to ethenes and ethynes in the presence of super bases to afford organylphosphines and -oxides has been performed.