Structure of Low-Coordinated Phosphorus (III) Compounds Including Phosphorus-Nitrogen Multiple Bond: 13C, 15N and 31P NMR Investigation |
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| Authors: | Alexander B Rozhenko Mark I Povolotskii Vitaliiv V Polovinko |
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| Institution: | Institute of Organic Chemistry, National Academy of Sciences of Ukraine , Kiev, Ukraine |
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| Abstract: | Abstract A wide series of low-coordinated phosphorus (III) compounds including iminophosphines 1, two- 2 or mono-coordinated 3 phosphorus-containing cations, and anion 4, where Mes? = 2,4,6-tris-(tert-butyl)phenyl, has been investigated by 13C, 15N and 31P NMR spectroscopy. The spectral parameters obtained are considered in connection with the ab initio (6–31G?) calculation data of the model compounds. |
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