The Synthesis and Acid-Catalyzed Hydrolysis of N-(4-Substitutedphenyl)-O-Benzenedisulfonimides |
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| Authors: | Yunus Bekdemir Bilge Eren Halil Kütük |
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| Institution: | 1. Department of Chemistry, Faculty of Science and Arts , Ondokuz May?s University , Kurupelit , Samsun , Turkey;2. Department of Chemistry, Faculty of Science and Arts , Bilecik University , Bilecik , Turkey |
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| Abstract: | Abstract The acid catalyzed hydrolyses of some cyclic disulfonimides, N-(4-substitutedphenyl)-o-benzenedisulfonimides (1a–d) have been studied in concentrated aqueous acidic solutions. Analysis of the data by the Excess Acidity Method, activation parameters, substituent, and solvent deuterium isotope effect are all indicate hydrolysis by an A-1 mechanism in the studied range. |
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| Keywords: | Disulfonimides acid-catalysis excess acidity hydrolysis mechanism |
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