Synthesis and Characterization of Zinc(II) Complexes with 3,4-Dimethoxybenzaldehyde Thiosemicarbazone: The Crystal Structure of [Zn(34-MBTSC)2Cl2] |
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| Authors: | Aliakbar Dehno Khalaji Gholamhossein Grivani Morteza Rezaei Karla Fejfarova Michal Dusek |
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| Institution: | 1. Department of Chemistry, Faculty of Science , Golestan University , Gorgan , Iran;2. School of Chemistry , Damghan University , Damghan , Iran;3. Institute of Physics ASCR, v.v.i. , Prague , Czech Republic |
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| Abstract: | Abstract The synthesis and characterization of three zinc(II) complexes Zn(34-MBTSC)2Cl2] (1), Zn(34-MBTSC)2Br2] (2), and Zn(34-MBTSC)2I2] (3) of 3,4-dimethoxybenzaldehyde thiosemicarbazone (34-MBTSC) are reported. Elemental analysis (CHN) and spectral (FT-IR and 1H-NMR) measurements have been used to characterize the complexes. In addition, the structure of the complex 1 has been determined by X-ray diffraction methods. In these complexes, the zinc(II) ion is bonded to two thioketonic sulfur donors in η1-S bonding mode and to two halide ions in tetrahedral geometry. Supplementary materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfer, and Silicon and the Related Elements for the following free supplemental files: Additional figures. |
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| Keywords: | Zinc(II) complexes thiosemicarbazone X-ray diffraction tetrahedral |
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