Synthesis and Structure of the Heterocyclic Phosphorus Containing Derivatives of [60] Fullerene |
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| Authors: | Oleg G Sinyashin Irina P Romanova Gulshat G Yusupova Valery I Kovalenko Yuri Y Efremov Irina I Vandyukova |
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| Institution: | A.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center , Kazan , 420088 , Russia |
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| Abstract: | Abstract Data on the structure of cycloadducts of organophosphorus dipolar reagents and fullerenes arc absent, to our knowledge. We died the reactions and the shucturc of cycloadducts of phosphorylated azidcs and nitrile oxide with 60]fullcrcnc. The cycloaddition of diphcnylphosphinic llzide to fullcrme has bcm determined to lead to the 1 -(N-diphenylphosphoryl)amino]-2-hydroxy6O]hllcrme (l), the mixhuc of phosphorylated aziridinofullcrcne (2) and derivative of fullerne (3) with one aziridine fragment and one aminohydmxy-fragment, or to product (4), depending on the conditions of don . |
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