Advances in Chalcogene Glycerophosphate Chemistry |
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| Authors: | D. A. Predvoditelev E. E. Nibantyev V. I. Lenin |
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| Affiliation: | Moscow State Pedagogical Institute , Malaya Pirogovskaya 1, Moscow , 119882 , USSR |
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| Abstract: | Abstract Achievements in the chemistry of trivalent phosphorus and phosphocyclic compounds find wide application in the synthesis of natural compounds. This paper provides fresh data on the possible use of these substances for the production of glycerophospholipids as well as their thio- and seleno-analogues. Thiol- and selenoanalogues of phosphatidylhomo-choline were obtained by a convenient thion-thiol/selenone-selenole isomerization of triester glycerophosphates in the presence of phosphonium salts as catalysts. |
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