Synthesis and Reaction Peculiarities of Phosphorylated Trifluoroethane Imines |
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| Authors: | Nikolai V Kolotylo Peter P Onys'ko Alexei A Sinitsa |
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| Institution: | Institute of Organic Chemistry, National Academy of Sciences , 5 Murmanskaya St, KIEV, 252660, UKRAINE |
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| Abstract: | Abstract Convenient methods for C,N - mono- and biphosphorylated trifluoroethane imines have been developed. These are reactive synthons allowing important derivatives of aminophosphonic acids, fluorine- and phosphorus-containing heterocycles, vinylamides, etc. A rare example of a Perkov-type reaction involving trifluoromethyl group has been discovered. |
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