From Neutral to Cationic Adducts: Investigations on the System Halogeno (Imino) Phosphane (Bisiminophosphorane)/DMAP |
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| Authors: | M Blättner A Ruban D Gudat M Nieger E Niecke |
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| Institution: | Institut für Anorganische Chemie , Gerhard-Domagk-Stra?e 1, D-53121 , Bonn , Germany |
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| Abstract: | Abstract Cations containing a unifold coordinated phosphorus center have been verified in the case of iminophosphenium salts 1a, and their chemistry has been explored i n some detail1b. Herein we report on the Lewis-acid/base reactions between halogeno-(imino)phosphanes (X?CI,Br,l) and the neutral amine-donor dimethylaminopyridine (DMAP). |
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