Copper(I) Complexes with Electron Deficient μ3-PRR′ Bridging - a Novel Coordination Mode of Secondary Phosphido Groups in Transition Metal Chemistry |
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Authors: | D J Brauer P C Knuppel O Stelzer |
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Institution: | Fachbereich 9, Anorg. Chemie, Bergische Universit?t-GH Wuppertal , Gau?stra?e 20, D-5600, Wuppertal 1 |
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Abstract: | Abstract Copper(1) phosphido complexes containing electron deficient μ3-PRR′ bridges are formed by P-Si cleavage reactions in silylphoshines with CuCl or by depolymerization of polymeric Cu(PPh2)]n with PMe3 or PMe3/CuCl. |
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