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Phosphorotropic Tautomerism in Amidine Systems |
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| Authors: | L. N. Markovsky V. I. Kalchenko V. V. Negrebetsky |
| Affiliation: | Institute of Organic Chemistry, Academy of Sciences of the UkrSSR , Murmanskaya St. 5, Kiev-94, 252660, USSR |
| Abstract: | Abstract During the last years considerable progress was made in the study of phosphorotropic tautomeric transformations, which involves quick reversible migrations of phosphorus groups between nucleophilic centers of molecule. Phosphorotropic systems may serve a s simple and clear models for study of the mechanism of substitution reactions at the phosphorus atom. |
| Keywords: | Triphenyltelluroniumdiorganylphosphinodithiocarbonates addition of Sulfur Triphenyltelluroniumthiophosphinoyldithiocarbonates elimination of CS2 Triphenyltelluroniumdiphenyldithiophosphinate Sodiumdiphenyldithiophosphinate |