Synthesis,Complexes and Metal Extraction Ability of R1R2NC(X)NHP(Y)(0Ph)2 |
| |
| Authors: | E Herrmann Nguyen Thi Thu Chau O Navratil G Ohms L Beyer |
| |
| Institution: | 1. Martin Luther University Hallo-Wittenberg , Yostfach , Ilalle , 4010 , GDR;2. J.E. Pur lcy ne University , Brno , CSSR;3. University of Teclinology Dresden , CDR;4. Institute of Technology Leipzig , GDR |
| |
| Abstract: | Abstract The new 1,1-disubstituted 3-diphenoxy(thio)phosphoryl-(thio)ureas, R1R2NC(X)NHP(0Ph)2, HA, with X,Y = O,S, were synthesized by addition of secondary mines to the corresponding P-iso(thio)cyanates. This reaction is reversible if X,Y = S. (PhO)2P(Y)Cl reacts with H2NC(X)NR2 in the presence of an HCl acceptor only if X,Y a 0. Side reactions are observed. Phosphorylated derivatives of biuret were isolated from such a reaction mixture. |
| |
| Keywords: | |
|
|
