Cycloaddition Reactions of the Metal Phosphorus Double Bonded Complexes CP(CO)2M=PR2 (M = MO,W; R = Alkyl,Aryl) |
| |
| Authors: | Wolfgang Reich Terry S. Bright Wolfgang Malisch Carl Kruger |
| |
| Affiliation: | 1. Institut für Anorganische Chemie der Universit?t Würzburg , Am Hubland, D-8700 , Würzburg , FRG;2. Max-Planck-Institut für Kohleforschung , Kaiser-Wilhelm-Platz 1, D-4330 , Mülheim , Ruhr , FRG |
| |
| Abstract: | Abstract The reaction of the metal phosphorus double bonded species Cp(CO)2M=PR2 (M = Mo, W; R = aryl, alkyl) (1)1) with diverse diazoalkanes, alkenes, alkines and dienes results in the facile formation of the [2+1]-, [2+2]1- and [2+4]-cycloaddition products 2a-c. |
| |
| Keywords: | |
|
|
