An Electrogenerated Base-Promoted Synthesis of 2-Aryl-3,3-Bis((Perfluoroalkyl) Thio)Acrylonitriles |
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| Authors: | Taieb Saied Noureddine Raouafi Khaled Boujlel |
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| Institution: | 1. Département de Chimie et de Biologie Appliquées , Institut National des Sciences Appliquées et de Technologie , B. P. 676, 1080 , Tunis Cedex , Tunisie;2. Laboratoire de Chimie Analytique et Electrochimie, Faculté des Sciences de Tunis , Université Tunis El-Manar , Campus Universitaire, 2092 , Tunis , Tunisia;3. Laboratoire de Chimie Analytique et Electrochimie, Faculté des Sciences de Tunis , Université Tunis El-Manar , Campus Universitaire, 2092 , Tunis , Tunisia |
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| Abstract: | Abstract The preparation of 2-aryl-3,3-bis((perfluoroalkyl)thio)acrylonitriles is described. The electrogenerated cyanomethyl base/anion obtained from electroreduction of acetonitrile promotes reactions between arylacetonitrile, carbon disulfide, and perfluoroalkyl iodides. The new fluorinated acrylonitriles were obtained in good yields under mild reaction conditions. |
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| Keywords: | 2-Aryl-3 3-bis((perfluoroalkyl)thio)acrylonitrile carbon disulfide anion EGBs |
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