Synthesis and Reactivity of New Organophosphorus Compounds

Abstract

Synthesis of functionally substituted organophosphorus compounds on the basis of reactions of the tri-n-butylphosphine/carbon disulfide, tri-n-butylphosphine/phenylisothiocyanate, tris(dimethylamino)phosphine/phenylisothiocyanate adducts with a wide range of different dipolarophiles are reported. The development of application of S-Li tri-n-butylphosphonio-dithioformiate derivatives to the synthesis of new types of organophosphorus compounds are reported.