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GAS/SOLID-REACTIONS WITH SULFUR COMPOUNDS
Authors:Gerd Kaupp  Doris Lübben  Olaf Sauerland
Institution:Fachbereich Chemie—Organische Chemie I— , Universit?t Oldenburg , Postfach 2503, D-2900, Oldenburg, Germany
Abstract:Abstract

The various types of gas/solid-reactions (addition, elimination, substitution, condensation, catalyzed cycloaddition) in different branches of sulfur chemistry (heterocycles, S-vinyl-compounds, thioethers, thiols, sulfur dioxide) are reviewed, new types and new synthetic applications added. The reactions run to completion in a short time. The advantages of avoiding solvents are discussed, some mechanistic hints obtained.
Keywords:Gas/solid-reactions  salt formation  addition reactions  S-vinyl compounds  thiols  sulfurdioxide  
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