Unusual Transformations of 2-Cyanoacrylates in Reactions with Trivalent Phosphorus Compounds |
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| Authors: | Yuri G Gololobov Tatiana O Krylova |
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| Institution: | A.N. Nesmeyanov Institute of Organo-Element Compounds Russian Academy of Sciences , Vavilov str., 28, Moscow V-334, 117813, GSP-1, Russia |
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| Abstract: | Abstract Cyanoacrylates 1 have existed for 40 years, but up till 1 only polymerization processes, effected by various nucleophiles, including trivalent phosphorus compounds, have been known. We have shown that under established conditions 1 (aR=Me, b R=Et) reacts with trivalent phosphorus compounds not only via the anionic polymerization pathway, but depending on the structure, it forms stable adducts2,4 or 5. |
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