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Synthesis and Reactivity of New 1,1-Diphenyl-2,5-Dihydrophospholium Salts
Authors:H.-J. Cristau  J. Grenier  E. Torreilles
Affiliation:Laboratoire de Chimie Organique , URA 458 E.N.S.C.M. 8 , Rue de l′école normale, 34053, Montpellier cedex, France
Abstract:Abstract

We describe the first synthesis of new 1,1-diphenyl-2,5-dihydrophospholium salts of type 1. These salts allow the access to interesting alkadienyl phosphine oxides 3 and trienes 4. Unfortunately we could not obtain the strong nucleophilic diylide 5.
Keywords:Dihydrophospholium Salts  ylides  Wittig Reaction  Trienes
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