Structure and Dynamical Behaviour of Bis(N-Diisopropoxy-Phosphorylthiobenzamido) Copper(II) |
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| Authors: | A L Kon'kin V G Shtyrlin N G Zabirov I A Litvinov A T Gubaidullin R R Garipov |
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| Institution: | Kazan State University , Kremlevskaya Str. 18, Kazan , 420008 , Russian Federation |
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| Abstract: | Abstract Among the new compounds of N-(thio)phosphorylthiómides. the copper(II) complex with N-diisopropoxyphosphorylthiohenzamide (Cul. 2) exhibits series of unusual properties which have been extcnsively investigated in the present work. The X-ray structure of CuL2 has been determined Crystals of CuL2 are monoclinic. P21/c, a = 15.610, b = 11.880, and c = 18.320 Å, β = 106.74°. Z = 4. The CuL2 complex has the cis-structure with Cu-S distances ranging from 2.238 to 2.253 Å and Cu-O distances being from 1.919 to 1.937 Å (Figure). |
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